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關於cp/cv k 在 Re: [學習] 熱力學新手Cp Cv問題- 看板Chemistry 的評價
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關於cp/cv k 在 Cp Cv ratio在PTT/mobile01評價與討論 - 房產建案資訊懶人包的評價
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cp/cv k 在 Re: [學習] 熱力學新手Cp Cv問題- 看板Chemistry 的推薦與評價

作者jaannddyy (詹敵)

看板Chemistry

標題Re: [學習] 熱力學新手 Cp Cv問題

時間Tue Feb 14 20:49:55 2017

推 iampao: 5/2R適用在單原子分子題目只說是理想氣體並未說明是單 02/12 22:03
→ iampao: 原子或雙原子或線性或非線性或者更複雜的分子所以只能以 02/12 22:03
→ iampao: 題目給的資訊來計算有錯麻煩更正～

原來是要單元子分子才可以使用 Cp=5/2R

可是目前在寫題目時又碰到一個疑惑

以我的理解,不曉得是否有錯

Cp-Cv=R 和 Cp/Cv=gamma=5/3

皆是從 Cv=3/2R 與 Cp=5/2R 來的

有一題目給予Cv=27.5J/K*mole (ideal gas)

在計算過程中會需要Cp值,我以Cp/Cv=5/3的關係代入去計算

卻錯了

詳解卻寫以Cp-Cv=R 代入計算,而兩值有所差別

兩個疑惑如下

1.一開始給予Cv值就無符合Cv=3/2R,為何最後卻用Cp-Cv=R來求Cp值呢?

2.既然可以使用Cp-Cv=R求Cp值d,為何不能使用Cp/Cv=5/3來求呢?

謝謝各位解惑~

--

※ 發信站: 批踢踢實業坊(ptt.cc), 來自: 220.134.59.46
※ 文章網址: https://www.ptt.cc/bbs/Chemistry/M.1487076598.A.B0F.html
※ 編輯: jaannddyy (220.134.59.46), 02/14/2017 20:50:33

推 x553066: 在理想氣體時，Cv可以由轉動、振動、移動自由度得出，並 02/14 21:03

→ x553066: 非每種氣體皆相同。 02/14 21:03

→ x553066: 當然的，Cv,Cp也差一個R是用計算所得，等到後面教完馬克 02/14 21:03

→ x553066: 思方程才可以全部一次性連起來(我學了還久，偶爾還是茫然 02/14 21:03

→ cvsh: Ideal gas的Cp-Cv必定等於R,在非理性氣體的熱力學性質會有 02/15 15:03

→ cvsh: 推導 02/15 15:03

→ cvsh: 而且，ideal gas的Cp和Cv並不是常數，而是溫度的函數。只有 02/15 15:08

→ cvsh: 在單雙原子氣體時才為常數，這也是為什麼你必須用Cp-Cv為R去 02/15 15:08

→ cvsh: 解 02/15 15:08

... <看更多>

cp/cv k 在 Explained: Specific Heats (Cp & Cv) - YouTube 的推薦與評價

Explained: Specific Heats ( Cp & Cv ). 11,823 views11K views. Nov 1, 2016 ... 18.5 K subscribers. Subscribe. In this video we will derive the ... ... <看更多>

cp/cv k 在 Cp Cv ratio在PTT/mobile01評價與討論 - 房產建案資訊懶人包的推薦與評價

Show that CP А CV ¼ TVa2 k . Thermodynamics and Introductory Statistical Mechanics, ... (b) If the gas is heated at constant pressure, show that Аw ¼. ... <看更多>

cp/cv k 在 Cp Cv ratio在PTT/mobile01評價與討論 - 房產建案資訊懶人包的推薦與評價

Show that CP А CV ¼ TVa2 k . Thermodynamics and Introductory Statistical Mechanics, ... (b) If the gas is heated at constant pressure, show that Аw ¼. ... <看更多>

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The total entropy change over the cycle is ∆S = ∆SBC +∆SCD +∆SDB = (CP CV R)ln V2 V1 = 0; as it should be. Click the play button next to "mix gases" to ...

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Now, simulate CP/CV z = 0.5; irc = 0; h = -1; % initialize to 50% SOC, resting CP = 35; % constant absolute power limit of 30 W in CP/CV charge for k = 1: ...

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C, que é a temperatura equivalente do zero absoluto (0 K). ... pressão constante, logo, Cp é maior que Cv. Para produzir o mesmo incremento.